1/5/2024 0 Comments Chemdoodle v8 user guide![]() ![]() menu item, choose the mapping algorithm, whether to overlap the structures, or allow inversions. A new function to align molecular structures in 3D.While minimizations of several discrete structures using through-space forces may look correct, please understand the theory behind the force field you are using and that any force field not specifically developed or parameterized for intermolecular forces will not lead to experimentally accurate coordinates. Please note, while you are able to optimize the entire scene, most force fields are not parameterized for multiple discrete molecular structures, and you will be relying on the through-space forces defined in the force field (mainly van der Waals and electrostatic), if defined at all. To do this, you can change the optimization scope to optimize the entire scene. However, you may wish to optimize several discrete molecular structures at the same time and in relation to each other. ChemDoodle 3D therefore will optimize molecular structures separately and individually as you are editing them. Most small molecule force fields are optimized for describing individual discrete molecular structures. ChemDoodle 3D now allows full scene modeling simulations.Major new features include the ability to perform full scene modeling simulations, an implementation of the FIRE optimizer, 3D molecular structure alignment, improved bond deduction with new bond order perception algorithms, and more. ChemDoodle 3D v6.6 is a feature update to ChemDoodle 3D.
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To do this, press the Start button and find the game. I personally encountered this issue myself and the effective fix that I discovered is to open the game (in my case Call of Duty Warzone) directly without opening the app. This should prevent another program from interfering with the new folder that you’ll install later on. If Battle.Net app still won’t go online after doing the steps, restart your PC and delete the folder again. Run and update the game to see if the issue persists. Type “C:\ProgramData\” (without the quotes) into the open field and press Enter. ![]() Once you’ve closed all the Blizzard processes, press Windows Key + R button to open the Run dialogue. Select all Agent, Blizzard desktop app, and game processes, and click End Process. Pull up Task Manager by pressing three buttons ( Ctrl + Shift + Esc) at the same time. This can work if the main reason is due to an outdated or corrupted ® folders or files. Some gamers have reported that deleting the folder fixes their problem. While the launcher is trying to log in, click on the region indicator to change it. There may be an issue on their end that affects certain websites or services that may not be obvious on your end.Īs mentioned above, using a different region can help. Second, you want to get help from your Internet Service Provider. Do a speed test to check if your connection is fast enough to open websites, or let you play online games. The next good step that you can do, assuming that there’s no server problems at all, is to check your own internet connection.įirst, try using a different device like a smartphone to see if your internet is fine. If this is the reason for your problem, there’s nothing much that you can do but wait until Activision figures out a solution. This is the most reliable way to know if there’s an on-going gaming server problem. ![]() If app was previously working on your computer but it’s no longer loading up now, you should make sure that you visit the Activision Twitter page to get answers. How to fix Battle.Net app won’t go online issueīelow are the solutions that you can try to fix a application that won't go online. You can perform a few troubleshooting steps to figure out what’s wrong with the app by following the solutions below. If there’s no gaming server maintenance/outage and your home network/ISP connection are working normally, the cause of the problem may be found in your computer, specifically the app itself. If there’s no indication from the official Activision support page about any on-going server outage, you may need to troubleshoot your home network or check with your ISP for support. Local network problem.Īnother possible cause why Battle.Net app may fail to go online can be an issue with your home network, or with your Internet Service Provider. This trick can sometimes work if only a certain region is having trouble. If you play on Americas server, try switching to other servers like Europe or Asia. You can visit the official Activision Twitter page so you’ll know if there’s any known server problem that impacts the game you want to play.Īt other times, issues can be region specific. If Battle.Net app won’t go online or keeps showing an error message/code saying so, the first thing that you should do is see whether or not there’s an on-going server issues. If you’re getting any particular error codes when trying to open the Blizzard client, the things below can be the reason for that. Some users have reported to us that their application simply refuses to even pull up and instead only shows certain error codes like BLZBNTBNA00000006 or BLZBNTBGS80000011. There could 3 possible causes if your Blizzard application, also known as client, won’t go online. Reasons why Battle.Net app won’t go online We’ll show you the common reasons why this issue happens as well as the solutions that you can try to fix it. If you can’t play your favorite game like Warzone because won’t go online, continue reading this article. Blizzard services may go down from time to time due to a number of factors. PlayOnMac is a Wine-based software for easy installation of Windows. * If you're prompted to open the app in Finder and you're sure you want to open it despite the warning, you can control-click the app, choose Open from the menu, and then click Open in the dialog that appears. Enter your admin name and password to open the app. For the installation on Mac OS we recommend to use the free application PlayOnMac.
1/5/2024 0 Comments Little tiny witch hat image![]() Put the cone on the circle, and bend the sticky side of the tape so that it sticks to the circle, inside the cone. Put about half of the tape on the inside of the cone, with half of the tape hanging down. To put the tape on the inside, cut off a small piece of tape. ![]() ![]() You can either just tape the outside of the cone, or stick the tape on the inside so that it’s less visible. Put your treat inside the cone, and then tape it to the circle. I recommend using the craft felt that is a little stiff, 2mm or less. This DIY will show you how to make the mini witch hat base and then you add your own style from there The three sizes are large 7.5 inches tall, medium 6 inches tall and small 4.5 inches tall. Once you reach the point, knot the thread and cut off excess. Starting at the bottom two corners of the 'hat top', whip stitch the. Starting at the bottom two corners of the 'hat top', whip stitch the hat together, coming up from the inside, over the seam, and back down. FREE Shipping on orders over 25 shipped by Amazon. Remove the template pieces and set aside. Small Witch Hat Retro Black Witch Flower Hair Clip Decorative Halloween Hair Accessories for Party (Black Flower) Medium (Pack of 1) 176. Also cut out the center of the hat buckle. Using a craft knife cut along the cut lines on the 'hat brim'. Decorated with our Black Flower Market pattern and orange polka dots, it features a small Courtly Check Owl on its brim. Then cut a circle for the bottom of the hat. Im using my new Cameo 4 with a deep cut blade and adapter with the craft foam settings. Steps: Use rolled pieces of tape to hold the template to the felt. To make the witch hats, roll a cone shape from black construction paper, and tape it. You will need: Hook 3.0 Black acrylic yarn Green acrylic yarn Headband Inc increase, sc single crochet, dec decrease size. Watch our new crochet tutorial and learn how to make this tiny witch hat. To go along with such a sweet witch, we made some candy treat witch hat cones! They were fun to hand out for the kids to nibble as we read. Stock Image by timurock 52 / 4,368 Big pumpkin with black witch hat and broom Stock Image by Sandralise 1 / 144 Witch's hat Picture by teine 1 / 30 Witch tools Stock Photography by clairev 1 / 318 Halloween set Stock Photography by katerinamk 13 / 271 Witch Hat Stock Photographs by lenm 6 / 136 Witch Kid Isolated Stock Photography by mkoudis 2. What about add a little evil to your Halloween costume We have a one cute idea. And my kids love the cute pictures and the three friends the witch picks up along the way. Refill prescriptions online, order items for delivery or store pickup, and create Photo. The rhyming and repetition in the book make it a fun to read aloud choice. Your go-to for Pharmacy, Health & Wellness and Photo products. Just ¼ inch thick Birch plywood that’s sturdy and made to last for holidays to come.We read Room on the Broom by Julia Donaldson for this month’s Virtual Book Club For Kids selection. This little girl is so cute with her purple and orange dress and orange hat Shes holding a small Orange. You’ll have a house and yard haunted not by ghosts, but by fabulous Halloween room décor!Ĭhoose Quality Wood- There’s nothing hocus pocus about our witch’s hat wood cutout. 196,433 witch hat stock photos, vectors, and illustrations are available royalty-free. Here is the latest addition to this collection. Just ¼ inch thick Birch plywood that’s sturdy and made to last for holidays to come. (Seal to make your craft weather resistant.)Ĭhoose Quality Wood- There’s nothing hocus pocus about our witch’s hat wood cutout. Take the spooky spirit outdoors with fabulous lawn signs and fall door hanging. Maximize The Wow, (And The Creeps!)- You’ve got walls, mantel, door, lawn, party table, and furniture to cover with fabulous Halloween crafts and decor, so let’s get decorating! Create personalized table settings or drill a hole through these sturdy wood cutouts and string them across the room. This charming accent of a ghost showing a silly expression wears a classic witchs hat and holds a pumpkin basket. Paint it black, orange, or purple or, if you dare, try glow-in-the-dark paint! Acrylic pours, collages, wood-burning, marker, or glitter, our witch’s hat unfinished wooden cutout is the perfect blank canvas for both adult and kiddie creativity. Little wrist tattoo of a witches hat and a star in the western sky- wizard of oz story book sketch- tribute to Wicked - witches hats represent female. Have a Spooky Good Time- Halloween means time for spellbinding decorations! Personalized, DIY fall décor is just the thing to get into the spooky October holiday spirit. 1/5/2024 0 Comments Bookpedia reviewsIt helps you keep track of which games you own and whether they're completed or unfinished. The focus for The Backloggery is to help you get through your backlog of unplayed games. The Backloggery Ī web-based option for tracking your games is The Backloggery. You can keep track of board games as well as video and computer games, and there's a bulk barcode scanner feature so you can quickly scan all of the games you own. You can share your ratings and read reviews by other users, and there are a couple of different export options. It's an Android app to help you keep track of the games you own, but it also lets you add ratings and notes to each game listing. Video Game Tracker Pro is quite similar to Game Keeper. You can also manually add anything that doesn't exist in the database, so you're not limited to the app's catalogue. It has an export feature so you can always take your data with you (something we're keen on). Game Keeper is an Android app for keeping track of games across multiple platforms, including retro games. This works just like Bookpedia and DVDpedia, but obviously it's for CDs instead. If you just want to keep track of new discoveries, this app could do the trick. It's a simple iPhone app that lets you create a todo list of music you want to buy or listen to later. Listenlist is a bit like TodoMovies for music. You can also connect most music services like Spotify, iTunes and Rdio to your last.fm account to track what you listen to (and get that data into Exist!) Listenlist It also recommends artists you might like and offers lots of ways to discover new music-explore by tag, related artists or what your friends are listening to. Last.fm pulls together lots of interesting stats about your listening history, including which artists you listen to most often, who you've recently listened to, and which tracks you play the most. I'm unclear as to whether you can track TV shows or not, but the focus is definitely on movie tracking. It's made by the same company and syncs to their iOS version, Pocketpedia (listed in the last section of this post). DVDpedia įor movie cataloguing, DVDpedia is essentially Bookpedia with a different focus. If you don't want to get a separate app for this, you can also create a Watchlist on IMDB to keep track of movies and TV shows you want to watch. TodoMovies is a simple todo list of movies you want to watch, with a discovery section built-in to help you keep up with new releases. You can also choose from a whole stack of third-party apps for iOS, Android and Windows Phone to manually track what you're watching. With a Trakt account you can connect to services like Popcorn Time, Apple TV and Plex to automatically track what you watch. Probably the most fully-featured service to track TV and movies is Trakt. If you're looking for a social way to keep track of what shows and movies you watch, this one is available on the web and for iOS and Android. After a recent rebrand to tvtag, it's now focused solely on movies and TV. ![]() Tvtag was previously branded as GetGlue and was a social network for checking in (a la Foursquare) to movies, TV shows, books, topics and even wines. You can add reviews and organise your books into collections. It's a Mac app that lets you add books by searching or scanning their barcodes, keep track of what you own, what you've loaned out and a wishlist of books you want to read. Bookpedia įor a less social, more data-focused approach to book tracking, you can try Bookpedia. If Goodreads isn't your thing, a couple of alternatives with similar social reading angles are LibraryThing and Readernaut. You can also get recommendations for new books to read based on what you've read before, which is handy. You can leave or read reviews, follow your friends, set a reading challenge for the year and browse quotes, polls and quizzes. ![]() Goodreads helps you track which books you're reading, what you've read in the past and a wishlist of books to read in the future. Hopefully these will get you started if you're looking for a way to keep an eye on what you're reading, watching and listening to. I've rounded up apps to track books, TV, games, music and movies, plus a few that track a bit of everything. Tracking the media you consume can be pretty fun. How many books have you read this month? How many do you read, on average in a year? How much time do you spend in front of the TV? What album did you listen to most last week? ![]() Movies, music, books and games: Apps to track your media 1/5/2024 0 Comments Sleep sounds![]() This helps so much with getting into the flow of writing when music doesn't help. ![]() This noise helps me focus on my work better than anything! :) You are taking shelter under a wooden roof during a long hike in the mountains. Now, I use it while sleeping and writing in my adult life. Ive used this for almost a decade now, would put it on in the background of my tumblr dives as a teen. No nonsense, no distractions, just steady, refreshing, soothing rain. I had been trying many different kinds of noises and music for work until I found this. ![]() I love it it is great for studying and helps me to relax!! Thanks <3 I work night shifts and this helps me sleep. Great for studying, stress-management and insomnia. The settings also make it perfect for my room/ears and I sometimes use it during the day to mask noises that are too foreign for me to concentrate. The rain in my headphones transports me to a place where there is no TV or other distractions.įor many reasons I'm very bad at falling asleep, but making the sound of rain + my comfort music a part of my routine at night before/during bed was one of the only things that helped. I can sleep, read or work at my desk with perfect focus. Writing instantly became easier for me! Thanks for helping me live vicariously haha But today is more blue & cloudy than usual, and I just HAD to break out this trusty site & put on my favorite music. I love the rain, but I don't get it often where I live. I love this so much it sounds so real with headphones! All the great sound of rain without waiting for a storm! Thank you so much for saving my llife!Īmazing for studying. What a great way to spend long days and nights trying to meet countless deadlines. I was doing math homework and getting frustrated, so I popped open this bookmark! Now I can finally finish trigonometry. I love this site! I live in a desert, but that doesn't stop me from loving rain. This is crazy, legit puts me in my childhood and opens up so many memories. Thanks so much to whoever made this website- you're a total G It helps me focus, calm down, and study! There are so many interesting sound combos I've made on here, some of which sound very realistic with headphones. I never realized how useful white noise could be. This helped me relax and get rid of and anger and problems I had. Countless hours have been spent learning weird math with this tab permanently open. This is pretty much the only way I've been able to study. I don't remember a night where I haven't used this app. It hasn’t rained like this in a while so this is the cure to my "disease" lolĪbsolutely amazing when your trying to study (like I am!). I love this rain noise! It really relaxes me while I'm studying. Very relaxing and soothing and helps me focus. Such great study music, especially when paired with 88 Keys. I'm really in a hurry with an assignment but this helps me to keep calm! Thank you! I never get enough thunder where I live, having this site is a calming blessing, thank you. Helps me prevent panic attacks and allows me to sleep more comfortably. I use this generator to mask low frequency noises that otherwise wouldn't be stopped by earplugs or earmuffs. ![]() It's just rain noise, but I can't thank it enough. I use it for so many things, & notably today when my sensory issues have been bothering me, I turned off the lights and turned on this plus some music, & I've slowly but surely been taken back to a calm place. I've been coming back to this generator for months on end now. Okay, I've already written a review for this one, but I had to say more. I've opened the 4 rain generators, gave the best setting to all of them, and then it was awesome, it made me remember my vacations in South Africa when I was a kid (with the giant tiger plush from back then I was still cudding with), it's perfect when I'm sick and just want to relax. The orange through green sliders all sound like rain hitting a shelter with various levels of insulation. The blue slider corresponds to the water hitting leaves and dirt and dripping from the canopy onto the ground. I like to imagine myself in a secure shelter in the wilderness with a canopy of trees. Rain is coziest when you're safe from it, but not isolated from it. Amazing! To drown out the office noise and still concentrate, the best! 1/4/2024 0 Comments Harmony assistant karaoke![]() WHAT SONG WOULD YOU SING AT KARAOKE NIGHT: “Don’t Stop Me Now” by QueenįAVORITE MOVIE: Shawshank Redemption, Back to the Future.įAVORITE TV SHOWS: TV Shows-Ozark, Breaking Bad, Big Bang Theory, Young Sheldon.įAVORITE BOOK: Outliers by Malcolm Gladwell.įAVORITE MIDDLETOWN RESTAURANT AND DISH: La Boca! I recommend the garlic, boneless wings! High school should not be seen as a stepping stone to college rather, an as a highly formative opportunity to fully develop as a caring and contributing human being. ![]() In fact, your years leading up should be punctuated by curiosity, creativity, and challenge a comfort in taking academic risks and the important lessons learned from mistakes stretching personally valuing authenticity and investing in your personal relationships and community. ![]() ONE PIECE OF ADVICE YOU'D GIVE TO ALL APPLICANTS: Applying to college is a process your education leading up to this point should not. WHY WESLEYAN? The Open Curriculum, advising system, and one-on-one engagement with the faculty will introduce you to new ideas and perspectives, push you outside of your academic comfort zone, and allow you to grow as an engaged scholar and socially conscious community member. WHAT SONG WOULD YOU SING AT KARAOKE NIGHT: Uptown Funk, Bruno Mars - I've been banned from Karaoke after an unfortunate debut at an undisclosed location in Upstate NY - As a act of Civil Disobedience I would quietly sing this as my "walk out" song : )įAVORITE BOOK: The Warmth of Other Suns, Isabel WilkersonįAVORITE MIDDLETOWN RESTAURANT: Haveli's lunch buffet - everything is tasty and it will satiate you and friends' varying dietary needs. Do your part and let the rest take care of itself. Your college outcomes are not accurate measures of either your self-worth or potential. Be your own best advocate and trust that it matters far less where you ultimately enroll than what you do while you are there. ONE PIECE OF ADVICE YOU'D GIVE TO ALL APPLICANTS: Remember that the college application process does not reward either the modest or the arrogant. The students are intellectually curious, socially and politically active, and invested in making positive impacts on the world regardless of what occupations they ultimately pursue. I was drawn to Wes as a student because it is exceptionally balanced in terms of size, location, educational philosophy, co-curricular opportunities, and more. WHY WESLEYAN? Few colleges afford the opportunity to take advantage of the breadth and depth of our academic programs in such a dynamically diverse community that promotes collaboration over competition. For a city of Middletown’s size the range of terrific and authentic ethnic food is outstanding. ![]() The Autobiography of Malcolm X, The Other Wes Moore, and My Beloved World by Supreme Court Justice Sonia Sotomayor top my list.įAVORITE MIDDLETOWN RESTAURANT: Puerto Vallarta is a long-time fave, but since Sultan’s Kebab Express opened up last spring it has quickly become a contender. WHAT SONG WOULD YOU SING AT KARAOKE NIGHT: Rebirth of Slick (Cool Like Dat) by Digable Planets because they rocked Spring Fling my senior year on Foss Hill.įAVORITE BOOK: I’m an avid reader of non-fiction and autobiographies are my “jam”. HOMETOWN and HIGH SCHOOL: Spanish Harlem, New York City, The Loomis Chaffee School ![]() Paying off externally held debt represents an outflow of wealth from the country. ![]() Paying off internally held debt is like the left hand paying the right hand dollars are redistributed, but there is no domestic loss of wealth. A $10,000 debt is a problem for someone with no income it is not a significant burden on someone earning $100,000 per year. ![]() It is analogous to an individual household: the level of mortgage and other debt is only a problem if the household does not have sufficient income (GDP) to keep up with monthly payments. Debt as a percentage of GDP is more relevant because it is a better measure of an economy’s, or government’s ability to manage that debt. However, only a portion of that (58 percent in 2004) is held by the public the remaining 42 percent is held by the Federal government – the government owes the money to itself. debt represents the total amount of money the Federal government owes to the owners of government securities. debt and the debt held by the public? Why is the debt as percentage of GDP more relevant than the total debt? Contrast the effects of paying off an internally held debt and paying off an externally held debt. The end of the stock bubble was the end of the budget surpluses.Ĩ. Also previous administration tax cuts were very much secondary in this picture, as were wars and the Medicare drug plan. The ending of this bubble was the biggest factor turning the surplus into a deficit. This gave us a recession which, although officially short and mild, led to the longest period without net job creation since the Great Depression (until the current downturn). By the summer of 2002 stocks had fallen to roughly half of their peak values destroying $10 trillion in wealth. Bubbles are not sustainable, by definition. The budget surplus story was due to the stock bubble, not tax cuts and budget restraint. Why did the budget surpluses in 20 give way to a series of budget deficits beginning in 2002? Why did those deficits increase substantially beginning in 2008? The overall effect of a rise in G is therefore dampened/ muted as it gets crowded out by rising interest rates.ħ. G rises to raise GDP, but the simultaneous rise in interest rates cause a fall in investment. if it is expected that tax rates will be lowered in future due to political considerations of winning an election, then a current policy of higher tax rates is not effective, making the fiscal policy weak.Ĭrowding out refers to the dampening of the effect of a rise in government expenditures on GDP. Expectations about future policy reversals keeping politics in mind can dent the effect of any announced policy. This decision maybe suboptimal for the economy, but optimal for the political party. It may take a decision that yields quicker results which it can show off to voters and get back into power. When this lag is large the government may not make a sound decision. How might “politics” complicate fiscal policy? How might expectations of a near-term policy reversal weaken fiscal policy based on changes in tax rates? What is the crowdingout effect and why might it be relevant to fiscal policy?Ī time lag refers to the time it takes for a policy to take effect- the time between a policy measure is announced and its effects are visible. Briefly state and evaluate the problem of time lags in enacting and applying fiscal policy. 1/4/2024 0 Comments Money manager ex vs ynab![]() And you can manually categorize or recategorize synced transactions. ![]() You can set your own categorization rules and color scheme, so your spreadsheets are always easy to follow. For example, if you spend $50 at the grocery store today, you’ll see it reflected in the groceries or food category on your spreadsheet tomorrow. Once you’re synced, Tiller Money makes daily updates to custom-created Google or Excel spreadsheets with automatically categorized transactions pulled from your synced accounts. ![]() If you bank, invest, or borrow with a U.S.-based financial institution, you should be able to sync most or all of your financial accounts with Tiller Money. Tiller Money is a spreadsheet-based app that directly syncs with nearly 20,000 financial sources, including deposit accounts at large and small banks in the United States, U.S.-based brokerage accounts, employer-sponsored retirement accounts, personal loans, credit cards, and mortgages. Features and Capabilities: Automatic syncing with tens of thousands of financial sources automatic daily spreadsheet updates with transaction data from all linked bank accounts and other financial accounts custom spreadsheet templates custom spending categories that make sense for your financial life auto-categorization based on custom rules set by you daily transaction digests sent to your email inbox.Plans: One plan for all features and capabilities ($79 per year after a 30-day free trial).To learn more, read our Personal Capital review. This tool helps you find and tally hidden and not-so-hidden fund and investment management fees to answer the age-old question that bedevils every investor: Are you spending more than necessary to manage your investments? ![]() Personal Capital uses this tool to push its wealth management services, but it’s useful nonetheless. Use this tool to compare your present investment portfolio allocations against ideal allocations for your age and risk tolerance. Use these tools to estimate how much you’ll need to retire and fund your kids’ higher education under various financial scenarios, then develop a plan to reach each goal. From here, you can sync external financial accounts (including external investment accounts) for better insight into your financial health metrics, including household cash flow, savings rate, and net worth. Your account dashboard is Personal Capital’s money management hub. Personal Capital’s budgeting and money management tools include: Personal Capital is a hybrid wealth management platform that’s among the best-regarded human-assisted robo-advisors in the business.īut Personal Capital also has a host of free budgeting and financial literacy tools designed to draw new clients into the fold and keep them engaged until they meet the platform’s $100,000 investable assets minimum.
1/4/2024 0 Comments Aria resort casinoOnsite safety features include a smoke detector.This property reserves the right to pre-authorize the guest's credit card prior to arrival.The credit card used at check-in for incidentals must be in the name of the primary guest who made the reservation.Certain requests may come with additional charges. ![]() Special requests are subject to availability at the time of check-in and can't be guaranteed. ![]()
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